Signal enhancement of J-HMQC experiments in solid-state NMR involving half-integer quadrupolar nuclei.
نویسندگان
چکیده
We show that for half-integer quadrupolar nuclei, the manipulation of the satellite transitions can accelerate and enhance coherence transfer to other isotopes. This novel strategy is demonstrated to improve the sensitivity of (31)P-{(27)Al} J-HMQC experiments for a layered aluminophosphate Mu-4.
منابع مشابه
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ورودعنوان ژورنال:
- Chemical communications
دوره 49 59 شماره
صفحات -
تاریخ انتشار 2013